Search results for "chemistry [Water]"
showing 10 items of 2369 documents
3‐D Architecture and Plio‐Quaternary Evolution of the Paola Basin: Insights Into the Forearc of the Tyrrhenian‐Ionian Subduction System
2020
Using seismic reflection profiles and bathymetric data, we analyzed the stratigraphy and tectonics of the Paola Basin, providing information on the dynamic of the forearc of the Tyrrhenian-Ionian subduction system. The Paola Basin is a NNW-SSE trending syncline, bounded by the Coastal Chain to the east and the Paola Anticline to the west. It hosts up to 5.2 km thick Plio-Quaternary deposits, most of them supplied from Apenninic/Sila entry points and transported by longshore currents. The total subsidence reaches a value of ∼5 km. The sedimentary load varies from 60% to 75% of the total subsidence. The Pliocene to Lower Pleistocene sedimentary infill of the syncline displays a strata growth …
Magmatism Along Lateral Slab Edges: Insights From the Diamante-Enotrio-Ovidio Volcanic-Intrusive Complex (Southern Tyrrhenian Sea)
2019
Volcanic‐intrusive complexes often formed along lateral slab edges as a consequence of subduction‐induced mantle flow. We investigate this process in the southern Tyrrhenian Sea by integrating multibeam bathymetry, seismic‐reflection data, regional magnetic anomalies data, and seismological data. The interpretation of the data highlights the presence of magmatic intrusions that locally reach the seafloor forming volcanic edifices. Chimneys, lava flows, and laccoliths are observed beneath and surrounding the volcanoes. The emplacement and cooling of the magma occurred during the Brunhes Chron. The volcanoes are not active even if the hydrothermal activity occurs. The volcanic‐intrusive compl…
Separation of di-n-propyl ether and n-propyl alcohol by extractive distillation and pressure-swing distillation: Computer simulation and economic opt…
2011
Abstract Azeotropic mixtures are impossible to separate by ordinary distillation. Two of the most common methods for separating a binary homogeneous azeotrope are pressure-swing distillation (PSD) and extractive distillation (ED). The PSD process is effective if the azeotropic composition changes significantly with pressure. The ED process is effective if a suitable solvent can be found. This paper compares these two alternatives to separate a mixture made up of 50 mol% of di-n-propyl ether and 50 mol% of n-propyl alcohol by means of a practical case of a plant to treat 12,000 Tm/year of this mixture. The simulation has been carried out satisfactorily by mean of a package of commercial soft…
Approach to the 1-propanol dehydration using an extractive distillation process with ethylene glycol
2015
Abstract The extractive distillation process exploits the capacity of some chemicals to alter the relative volatility between the components of a mixture. In this way, a third component (called entrainer) may be added to an azeotropic binary mixture to break the azeotrope. This paper discusses the potential use of ethylene glycol as entrainer in a 1-propanol dehydration process by extractive distillation. First, the present work focuses on the acquisition of isobaric vapor–liquid equilibrium data of the ternary system 1-propanol + water + ethylene glycol system and the binaries systems 1-propanol + ethylene glycol and water + ethylene glycol. All measurements were done at 101.3 kPa. The exp…
In situ ATR-IR studies in aqueous phase reforming of hydroxyacetone on Pt/ZrO2 and Pt/AlO(OH) catalysts: The role of aldol condensation
2018
Abstract In situ Attenuated Total Reflection Infrared (ATR-IR) spectroscopy was used to study Aqueous Phase Reforming of hydroxyacetone on Pt/AlO(OH) and Pt/ZrO2 catalysts at 230 °C/ 30 bar. Formation of strongly adsorbed aldol condensation products was observed on the surface of Pt/ZrO2 and ZrO2 in contrast to Pt/AlO(OH) and AlO(OH). Peak assignments were supported by DFT calculations of the IR spectra of the condensation products in vacuum and in the presence of water. Aldol condensation of hydroxyacetone leading to compounds with high molecular weight with unsaturated bonds was suggested as a first step in coke formation. Carbonaceous deposits on the surface of the ZrO2 support are oxyge…
An inter-laboratory validation of methods of lipid peroxidation measurement in UVA-treated human plasma samples
2010
Lipid peroxidation products like malondialdehyde, 4-hydroxynonenal and F2-isoprostanes are widely used as markers of oxidative stress in vitro and in vivo. This study reports the results of a multi-laboratory validation study by COST Action B35 to assess inter-laboratory and intra-laboratory variation in the measurement of lipid peroxidation. Human plasma samples were exposed to UVA irradiation at different doses (0, 15 J, 20 J), encoded and shipped to 15 laboratories, where analyses of malondialdehyde, 4-hydroxynonenal and isoprostanes were conducted. The results demonstrate a low within-day-variation and a good correlation of results observed on two different days. However, high coefficie…
Aerosol radiative forcing efficiency in the UV region over southeastern Mediterranean: VELETA2002 campaign
2007
Atmospheric aerosol effects on spectral global UV irradiance were evaluated during the VELETA2002 field campaign between 8 and 19 July 2002 in southeast Spain. In the first stage, seven UV spectroradiometer and six CIMEL Sun photometer measurements were carried out simultaneously, allowing them to be calibrated and intercompared. The mean ratio obtained for the global irradiance between the spectroradiometers, with regards to a reference instrument, ranges from 0.98 up to 1.04 with standard deviations that oscillate between ±0.01 and ±0.17. In particular, the two spectroradiometers used to obtain the aerosol forcing efficiencies have a ratio of 1.000 ± 0.001. The aerosol optical depth (AOD)…
Partial melting of metabasic rocks and the generation of tonalitic–trondhjemitic–granodioritic (TTG) crust in the Archaean: Constraints from phase eq…
2020
Abstract Rocks of tonalitic–trondhjemitic–granodioritic (TTG) composition preserved in Archaean terranes represent fragments of the Earth’s earliest-formed continental crust, and are thought to have formed via partial melting of hydrated metabasalt. The geodynamic environments in which such high-grade metamorphism and anatexis may have occurred in the early Earth is strongly debated. Constraining the pressure ( P ) and temperature ( T ) conditions at which melts of appropriate composition can be derived from protoliths containing plausible mineral assemblages is central to addressing this question. Phase equilibrium modelling has been undertaken for an enriched Archaean tholeiite bulk compo…
Unraveling the exhumation history of high-pressure ophiolites using magnetite (U-Th-Sm)/He thermochronometry
2020
International audience; Magnetite is a ubiquitous oxide in ultramafic and mafic rocks, which is present in a large range of geological and tectonic settings. In the case of high-pressure ultramafic rocks, exhumation timing is commonly constrained by geochronometers in nearby lithologies. The development of the magnetite (U-Th-Sm)/He method (MgHe) has opened new perspectives to refine the exhumation history of such rocks. However no thermal history has been deduced using MgHe data so far. Here we applied MgHe dating to magnetite from an HP-LT alpine ophiolite body (Rocher Blanc) from the Schistes lustres units (Western Alps, France) where part the P-T-t history is constrained to further refi…
Reworking of the Tarim Craton by underplating of mantle plume-derived magmas: Evidence from Neoproterozoic granitoids in the Kuluketage area, NW China
2011
Abstract Most Neoproterozoic granitoids in the Kuluketage area, northern Tarim Craton are characterized by strongly depleted HREE abundances and high Sr/Y and (La/Yb) N ratios, showing typical geochemical features of adakitic rocks. Zircon U–Pb dating of three adakitic plutons yielded Neoproterozoic ages (754 ± 4, 790 ± 3 and 798 ± 3 Ma). The adakitic granitoids exhibit low MgO and TiO 2 contents. Their low Cr, Co and Ni abundances, low ɛ Hf ( t ) values (−21 to −11) and high FeO T /MgO ratios (mostly 2.2–2.9) preclude the possibility of being derived from partial melts of delaminated lower crust. The relatively low ɛ Hf ( t ) values and old Hf two-stage model ages ( T DM 2 = 2 . 42 – 3 .0 …